3D4M Ultra Performance

PI Z2 Filament.

A thermoplastic polyimide for the ultra-performance class, built to be easy to print. It meets EN 45545 R22 and R23 at HL3 for railway vehicles. read further

  • Easy to print HT filament
  • Extremely high Z strength
  • High insulating properties
PI Z2 Filament, Natural, 750 g, 1.75 mm
Configure
Color
Diameter
Weight
€899.95
€1,199.93/kg · excl. VAT
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Freshly produced on demand and typically shipped within 3 working days.

About this material

PI filament: PI Z2 is a printable polyimide certified for rail interiors.

PI Z2 is a printable thermoplastic polyimide. It belongs at the top of the range alongside PEEK, PEI and PEKK, and what it brings to that group is easy printing.

That printability is a commercial argument, not a comfort one: easy printing means high yield and fewer reject parts, and at this price per kilo the reject rate is a real line in the budget. Low warpage helps the part stay on the bed, and mechanical strength holds up in the Z direction as well as in plane.

It is inherently flame retardant and certified against EN 45545 requirement sets R22 and R23 at HL3, which makes it suitable for railway vehicle applications. Its Z strength makes it a candidate for thin-walled high-performance parts such as pressure vessels and connectors, and for harsh environments generally.

It is built on bio-inspired monomers, which is where its tunable performance and its sustainability story come from.

PI Z2 Filament

A bracket printed in PI Z2.

Physical properties
PropertyConditionValueTest method
Density 1.51 g/cm3 ASTM B923-10
Mechanical properties
PropertyConditionValueTest method
Tensile Strength XY (flat), printed bar 83 MPa ISO 527 Type 1BA
Tensile Strength XZ (on edge), printed bar 89 MPa ISO 527 Type 1BA
Tensile Strength ZX (upright), printed bar 68 MPa ISO 527 Type 1BA
Tensile Modulus XY (flat), printed bar 2.73 GPa ISO 527 Type 1BA
Tensile Modulus XZ (on edge), printed bar 2.89 GPa ISO 527 Type 1BA
Tensile Modulus ZX (upright), printed bar 2.56 GPa ISO 527 Type 1BA
Strain at Break XY (flat), printed bar 4.8 % ISO 527 Type 1BA
Strain at Break XZ (on edge), printed bar 4.8 % ISO 527 Type 1BA
Strain at Break ZX (upright), printed bar 3.5 % ISO 527 Type 1BA
Tensile Strength XZ (on edge), water-jetted bar 101 MPa ASTM D638 type V
Tensile Strength ZX (upright), water-jetted bar 59 MPa ASTM D638 type V
Tensile Modulus XZ (on edge), water-jetted bar 2.82 GPa ASTM D638 type V
Tensile Modulus ZX (upright), water-jetted bar 2.57 GPa ASTM D638 type V
Strain at Break XZ (on edge), water-jetted bar 4.5 % ASTM D638 type V
Strain at Break ZX (upright), water-jetted bar 2.7 % ASTM D638 type V
Tensile Strength ZX (upright), single wall 96 MPa ASTM 1708
Tensile Modulus ZX (upright), single wall 2.41 GPa ASTM 1708
Strain at Break ZX (upright), single wall 4.7 % ASTM 1708
Impact Strength Izod (notched) XY (flat) 5.3 kJ/m2 ISO 180
Impact Strength Izod (notched) XZ (on edge), water-jetted bar 5.3 kJ/m2 ISO 180
Impact Strength Izod (notched) ZX (upright), water-jetted bar 4.3 kJ/m2 ISO 180
Impact Strength Izod (unnotched) XY (flat) 29 kJ/m2 ISO 180
Impact Strength Izod (unnotched) XZ (on edge), water-jetted bar 28 kJ/m2 ISO 180
Impact Strength Izod (unnotched) ZX (upright), water-jetted bar 26 kJ/m2 ISO 180
Thermal properties
PropertyConditionValueTest method
Temp. of deflection under load 1.80 MPa 167 ºC ISO 75-1/-2
Temp. of deflection under load 0.45 MPa 175 ºC ISO 75-1/-2
Glass transition temperature (Tg) 195 ºC DMA
Decomposition temperature at 1% loss 343 ºC DMA
Decomposition temperature 460 ºC DMA
CLTE -45/45 infill, -50 to 60 ºC, probe on top face (XY) 43.05 ppm/ºC ASTM E831
CLTE -45/45 infill, -50 to 60 ºC, probe on side face (XZ/ZX) 46.64 ppm/ºC ASTM E831
CLTE -45/45 infill, 60 to 120 ºC, probe on top face (XY) 53.95 ppm/ºC ASTM E831
CLTE -45/45 infill, 60 to 120 ºC, probe on side face (XZ/ZX) 58.52 ppm/ºC ASTM E831
CLTE -45/45 infill, 120 to 190 ºC, probe on top face (XY) 62.51 ppm/ºC ASTM E831
CLTE -45/45 infill, 120 to 190 ºC, probe on side face (XZ/ZX) 67.74 ppm/ºC ASTM E831
CLTE 90º XZ infill, -50 to 60 ºC, probe on top face (XY) 50.15 ppm/ºC ASTM E831
CLTE 90º XZ infill, -50 to 60 ºC, probe on side face (XZ/ZX) 44.68 ppm/ºC ASTM E831
CLTE 90º XZ infill, 60 to 120 ºC, probe on top face (XY) 61.07 ppm/ºC ASTM E831
CLTE 90º XZ infill, 60 to 120 ºC, probe on side face (XZ/ZX) 58.30 ppm/ºC ASTM E831
CLTE 90º XZ infill, 120 to 190 ºC, probe on top face (XY) 68.64 ppm/ºC ASTM E831
CLTE 90º XZ infill, 120 to 190 ºC, probe on side face (XZ/ZX) 65.23 ppm/ºC ASTM E831
Electrical properties
PropertyConditionValueTest method
Dielectric constant 1 GHz 2.87 ASTM D150
Dielectric constant 10 GHz 2.85 ASTM D150
Dielectric loss 1 GHz 0.0094 ASTM D150
Dielectric loss 10 GHz 0.0083 ASTM D150
Breakdown voltage 172 MV/m ASTM D149
Printer settings & data sheets

A heated chamber, and a wide speed window once you are in it.

Print at 390 to 410 °C on a bed between 120 and 160 °C, in a heated chamber between 80 and 160 °C. This is not an open-printer material. For adhesion you have options: Magigoo HT, a nano polymer adhesive or GeckoTec EZ-Hot, on glass or a carbon plate.

Dry it first.

Pre-drying is mandatory: 120 °C for more than four hours. Once the machine is set up the speed window is unusually broad for this class, so the preparation is where the work is.

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Recommended print settings
ParameterValue
Nozzle temperature390 to 410 °C
Heated bed temperature120 to 160 °C
Print speed15 to 150 mm/s
AdhesionMagigoo HT, Nano polymer adhesive or GeckoTec EZ-Hot, on glass or a carbon plate
Drying120 °C, more than 4 hours
Chamber temperature80 to 160 °C
Nozzle0.4 mm or larger, ruby or hardened preferred
Bed materialGlass or a carbon plate
Empty spool weight
Filament weightSpoolEmpty weight
200 to 750 g RS 200 GH2L PC 243 g
Measurements & tolerance

Precision-engineered consistency.

Consistent prints start with a uniform filament shape. We continuously monitor diameter and roundness during production. When filament varies in size or loses its round profile, material flow becomes erratic. This causes under-extrusion and weak layer bonds.

Our manufacturing process keeps the cross-section stable across the full spool. Your printer receives a steady volume of material without pressure drops in the nozzle. You get predictable extrusion on every job, so with PI Z2 you can focus on your design, not your material.

1.75 mm filament
±0.05mm
Diameter tolerance, edge to edge across the spool.
2.85 mm filament
±0.10mm
Diameter tolerance, edge to edge across the spool.
Both diameters
≥95%
Cross-section roundness across the spool.
The production process

Sealed at the source. Never touched by water.*

Unlike manufacturers who cool filament in a water bath, our filament never touches water during production. Moisture inside the material creates bubbles and weakens layer bonding during printing. Water-free production keeps extrusion consistent and bubble-free.

Sealed and ready to print.
We produce on demand. Every spool is vacuum-sealed immediately after extrusion, so it reaches you dry. This process keeps every spool of PI Z2 ready to print out of the box.

* At times of high demand, and for some variants, production may run on a conventional water-cooled line. Contact us before ordering if you require material produced with our water-free process.

Vacuum-sealed filament spool, straight off the extrusion line

Vacuum-sealed on the production line, before it ever leaves the machine.

Traceability & quality assurance

Precision you can track. From pellet to part.

We produce every spool on demand in our own facility. This gives us direct oversight that mass-produced stock lacks. Your spool comes from a fresh, identifiable batch rather than long-term warehouse inventory. We document the production trail for every run.

Documented, not just shipped.
We keep the production logs for every batch we make. On request, we link a Certificate of Analysis and Technical Data Sheet to your specific batch. You get clear data for your spool of PI Z2.

About 3D4M

Dutch engineering for parts that define the future.

At 3D4M, we develop and manufacture high-performance thermoplastic filaments for demanding applications across aerospace, defence, semiconductor, automotive, medical research, and industrial manufacturing. We work with engineers, researchers, and manufacturers who need materials that go beyond standard specifications.

Our engineering starts with the machines themselves. We design and build our own extrusion lines around our patented extrusion process, combining material expertise with technology developed in-house. For moisture-sensitive polymers, our air-cooling technology offers a water-free cooling option, allowing us to tailor the production process to the material.

Our production facility is built on a single, uncompromising principle: control. From our extrusion technology to precise diameter monitoring and vacuum-sealed packaging, we control every stage to deliver consistent filament with batch traceability.

Trusted by global leaders
Supporting over 100 universities alongside global industry leaders, we have become a trusted partner to advanced research labs and manufacturers worldwide. We bring together material expertise and Dutch engineering to help turn ambitious ideas into reliable, high-performance parts.

3D4M headquarters in Haarlem, the Netherlands

3D4M headquarters, Haarlem, the Netherlands.

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Talk to an engineer

Validating this material for your application?

The leap to a high-performance polymer can be complex. Speak directly with one of our material engineers about your printer setup, target specifications, and material performance. We are here to help you de-risk your validation phase.

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Specify your specs. We'll start your batch.

Experience the benefits of freshly extruded, water-free filament. Select your required diameter and spool weight in the order panel to initiate our on-demand production process. We ship worldwide, vacuum-sealed and ready.

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